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Fortran format (5F11.5) bad value

I'm using a Fortran program to sum the orbitals coefficients. At first I use the following program:

Original file MOs_sum.f90 looks like this

  MOnumber = 1
  do i = 1,nsnaps_alpha
     read(20,'(a80)')string
     read(20,*)EMO(1),EMO(2),EMO(3),EMO(4),EMO(5)
     do j = 1,8
     **Line 51** read(20,*)coef_Li1(j,1),coef_Li1(j,2),coef_Li1(j,3),coef_Li1(j,4),coef_Li1(j,5)
     enddo
      do j = 1,8
         read(20,*)coef_Li2(j,1),coef_Li2(j,2),coef_Li2(j,3),coef_Li2(j,4),coef_Li2(j,5)
     enddo
     do j = 1,19
         read(20,*)coef_C3(j,1),coef_C3(j,2),coef_C3(j,3),coef_C3(j,4),coef_C3(j,5)
     enddo
      do j = 1,19
         read(20,*)coef_C4(j,1),coef_C4(j,2),coef_C4(j,3),coef_C4(j,4),coef_C4(j,5)
     enddo
     do ii = 1,5
         coef_Li1_sum = 0.0d0
         coef_Li2_sum = 0.0d0
         coef_C3_sum = 0.0d0
         coef_C4_sum = 0.0d0
     do j = 1,8
            coef_Li1_sum = coef_Li1_sum + coef_Li1(j,ii)*coef_Li1(j,ii)
            coef_Li2_sum = coef_Li2_sum + coef_Li2(j,ii)*coef_Li2(j,ii)
         enddo
     do j = 1,19
            coef_C3_sum = coef_C3_sum + coef_C3(j,ii)*coef_C3(j,ii)
            coef_C4_sum = coef_C4_sum + coef_C4(j,ii)*coef_C4(j,ii)
         enddo
         write(30,100)MOnumber,EMO(ii),coef_Li1_sum,coef_Li2_sum,coef_C3_sum,coef_C4_sum
         MOnumber = MOnumber + 1
     enddo
  enddo
  100   format(i6,2x,5(f20.5,5x))

And I obtain this error:

At line 51 of file MOs_sum.f90 (unit = 20, file = 'raw_MOs.txt') Fortran runtime error: Bad real number in item 4 of list input

I know the problem is caused by a large number in one column that intersects with another column (in the input). To solve it, I tried to use 5F11.5 format in read command. But I obtain the following error:

At line 49 of file MOs_sum.f90 (unit = 20, file = 'raw_MOs.txt') Fortran runtime error: Bad value during floating point read

raw_MOs.txt looks like this

 -19.66145  0.00177  0.00005  0.00005  0.00266
 -19.65987  0.00099  0.00032  0.00011  0.00120
 -10.59358  0.00017  0.00012  0.00006  0.00036

And the file MOs_sum.f90 looks like this (see line 49):

  MOnumber = 1
  do i = 1,nsnaps_alpha
     read(20,'(a80)')string
 **Line 49**  read(20,"(5F11.5)")EMO(1),EMO(2),EMO(3),EMO(4),EMO(5)
     do j = 1,8
    read(20,"(5F11.5)")coef_Li1(j,1),coef_Li1(j,2),coef_Li1(j,3),coef_Li1(j,4),coef_Li1(j,5)
     enddo
      do j = 1,8
         read(20,"(5F11.5)")coef_Li2(j,1),coef_Li2(j,2),coef_Li2(j,3),coef_Li2(j,4),coef_Li2(j,5)
     enddo
     do j = 1,19
         read(20,"(5F11.5)")coef_C3(j,1),coef_C3(j,2),coef_C3(j,3),coef_C3(j,4),coef_C3(j,5)
     enddo
      do j = 1,19
         read(20,"(5F11.5)")coef_C4(j,1),coef_C4(j,2),coef_C4(j,3),coef_C4(j,4),coef_C4(j,5)
     enddo
     do ii = 1,5
         coef_Li1_sum = 0.0d0
         coef_Li2_sum = 0.0d0
         coef_C3_sum = 0.0d0
         coef_C4_sum = 0.0d0
     do j = 1,8
            coef_Li1_sum = coef_Li1_sum + coef_Li1(j,ii)*coef_Li1(j,ii)
            coef_Li2_sum = coef_Li2_sum + coef_Li2(j,ii)*coef_Li2(j,ii)
         enddo
     do j = 1,19
            coef_C3_sum = coef_C3_sum + coef_C3(j,ii)*coef_C3(j,ii)
            coef_C4_sum = coef_C4_sum + coef_C4(j,ii)*coef_C4(j,ii)
         enddo
         write(30,100)MOnumber,EMO(ii),coef_Li1_sum,coef_Li2_sum,coef_C3_sum,coef_C4_sum
         MOnumber = MOnumber + 1
     enddo
  enddo
  100   format(i6,2x,5(f20.5,5x))

I've tried different modifications of the format but I didn't get any result. Any help would be greatly appreciated!

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